翻訳と辞書 Words near each other ・ Methylprednisolone ・ Methylprednisolone aceponate ・ Methylpyridinium ・ Methylquercetagetin 6-O-methyltransferase ・ Methylquercetin ・ Methylrhenium trioxide ・ Methylscopolamine bromide ・ Methylselenocysteine ・ Methylserotonin ・ Methylsilane ・ Methylsterol monooxygenase ・ Methylsulfonylmethane ・ Methyltestosterone ・ Methyltetrahydroprotoberberine 14-monooxygenase ・ Methylthioadenosine nucleosidase ・ Methylthioirontricarbonyl dimer ・ Methylthiomethyl ether ・ Methylthioribulose 1-phosphate dehydratase ・ Methylthiouracil ・ Methyltransferase ・ Methyltransferase 2 ・ Methyltrichlorosilane ・ Methyltrimethoxysilane ・ Methyltyramine ・ Methylumbelliferone ・ Methylumbelliferyl-acetate deacetylase ・ Methylvanillylecgonine ・ Methyphobia ・ Methyprylon ・ Methysergide Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Methylthioirontricarbonyl dimer ： ウィキペディア英語版 Methylthioirontricarbonyl dimer Methylthioirontricarbonyl dimer, also known as methanethiolatoirontricarbonyl dimer, is an organometallic compound with the formula Fe2(SCH3)2(CO)6. It is a red volatile solid that is classified as a transition metal thiolate complex. It exists as air-stable red crystals with two isomers, where the methyl groups are either ''anti'' (isomer A) or ''syn'' (isomer B) with respect to each other.〔King, R. B. "Organometallic Synthesis, Volume 1: Transition-metal compounds" (1965) Academic Press. ISBN 0124080502〕 ==Synthesis== It was first synthesized 1940〔Hieber, W., Scharfenberg, C. "Einwirkung organischer Schwefelverbindungn auf die Carbonyle des Eisens" ''Chem. Ber.'' 1949, vol. 73, 1012. 〕 with the discovery of isomers in 1962.〔King, R. B. "Organosulfur Derivatives of Metal Carbonyls. I. The Isolation of Two Isomeric Products in the Reaction of Triiron Dodecacarbonyl with Dimethyl Disulfide" ''J. Am. Chem. Soc.'' 1962, vol. 84, 2460. 〕 Synthesis involves treating triiron dodecacarbonyl with dimethyl disulfide: :2 Fe3(CO)12 + 3 (CH3)2S2 → 3 ()2 + 6 CO It can be purified by recrystallization or by sublimation. The isomers can be separated by chromatography using pentane in an alumina column. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Methylthioirontricarbonyl dimer」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.